A Second-Generation Chameleon N-Heterocyclic Carbene–Borane Coinitiator for the Visible-Light Oxygen-Resistant Photopolymerization of Both Organic and Water-Compatible Resins

Aubry, Bérengère; Subervie, Daniel; Lansalot, Muriel; Bourgeat‐Lami, Élodie; Graff, Bernadette; Morlet‐Savary, Fabrice; Dietlin, Céline; Fouassier, Jean‐Pierre; Lacôte, Emmanuel; Lalevée, Jacques

doi:10.1021/acs.macromol.8b01669

Public

A Second-Generation Chameleon N-Heterocyclic Carbene–Borane Coinitiator for the Visible-Light Oxygen-Resistant Photopolymerization of Both Organic and Water-Compatible Resins

Published in Macromolecules • Nov 26, 2018

Authors:

Bérengère Aubry

Daniel Subervie

Muriel Lansalot

Abstract

N-Heterocyclic carbene–boranes (NHC-boranes, NHCBs) were recently described as efficient coinitiators for the visible light photopolymerization of hydroxyethyl methacrylate (HEMA) in the presence of water. In this work, a new, more water-soluble, NHC-borane—2,4-dimethyl-1,2,4,5-tetrazol-3-ylidene bo...

Subject

Photopolymer

Methacrylate

Boranes

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