Mechanism unravelling for ultrafast and selective 99TcO4− uptake by a radiation-resistant cationic covalent organic framework: a combined radiological experiment and molecular dynamics simulation study

He, Linwei; Liu, Shengtang; Chen, Long; Dai, Xing; Li, Jie; Zhang, Mingxing; Ma, Fuyin; Zhang, Chao; Yang, Zaixing; Zhou, Ruhong; Chai, Zhifang; Wang, Shuao

doi:10.1039/c9sc00172g

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Mechanism unravelling for ultrafast and selective 99TcO4− uptake by a radiation-resistant cationic covalent organic framework: a combined radiological experiment and molecular dynamics simulation study

Shared by NobleBlocks on Jan 1, 2019 • 12:00 AM UTC

Authors:

Linwei He

Shengtang Liu

Long Chen

Abstract

Separation of TcO 4 – by a cationic covalent organic framework is achieved for the first time, showing advantages of extremely fast sorption kinetics, ultrahigh uptake capacity, good anion-exchange selectivity, and excellent radiation resistance.

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