Silylated Ge<sub>9</sub> Clusters as New Ligands for Cyclic (Alkyl)amino and Mesoionic Carbene Copper Complexes.

LJ, Schiegerl; M, Melaimi; DR, Tolentino; W, Klein; G, Bertrand; TF, Fässler

doi:10.1021/acs.inorgchem.8b03338

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Silylated Ge9 Clusters as New Ligands for Cyclic (Alkyl)amino and Mesoionic Carbene Copper Complexes.

Shared by NobleBlocks on Feb 11, 2019 • 12:00 AM UTC

Authors:

Schiegerl LJ

Melaimi M

Tolentino DR

Abstract

The coordination of Ge9 Zintl clusters at (carbene)CuI moieties is explored, and the complexes [(CAAC)Cu]2[η3-Ge9{Si(TMS)3}2] (1), (CAAC)Cu[η3-Ge9{Si(TMS)3}3] (2), and (MIC)Cu[η3-Ge9{Si(TMS)3}3] (3) are compared with their known N-heterocyclic carbene (NHC) derivatives (A and B), where CAAC = cyclic...

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