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Surprising discoveries on the way to an old compound: four transient iodido antimonates.

Published in Dalton transactions (Cambridge, England : 2003) • Apr 16, 2019
Authors:
Natalie Dehnhardt
,
André Böth
,
Johanna Heine

Abstract

During the synthesis of the literature-known iodido antimonate [Cu(MeCN)4]4[Sb3I11]2 (MeCN = acetonitrile), four transient compounds, [Cu(MeCN)4]4[Sb6I22]·2MeCN (1), [Cu(MeCN)4]4[Sb7I25]·MeCN (2), [Cu(MeCN)4]4[Sb10I34] (3) and [Cu(MeCN)4]4[Sb8I28] (4), were identified. The compounds appeared within ...

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