Stable Postfullerene Solar Cells via Direct C–H Arylation Polymerization. Morphology–Performance Relationships

J. Aldrich, Thomas; Zhu, Weigang; Mukherjee, S.; J. Richter, Lee; Gann, Eliot; M. DeLongchamp, Dean; Facchetti, Antonio; S. Melkonyan, Ferdinand; J. Marks, Tobin

doi:10.1021/acs.chemmater.9b01741

Public

Stable Postfullerene Solar Cells via Direct C–H Arylation Polymerization. Morphology–Performance Relationships

Published in Chemistry of Materials • May 16, 2019

Authors:

Thomas J. Aldrich

Weigang Zhu

S. Mukherjee

Abstract

The scope of the environmentally benign direct C–H arylation polymerization (DARP) process is validated and significantly extended in the synthesis of a high-performance benzodithiophene-based copolymer series, PBDT(Ar)-FTTE, with previously untested and systematically varied heteroaryl (Ar) substit...

Subject

Polymer solar cell

Materials science

Copolymer

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