Crystal Structure, Electronic Structure, and Temperature-Dependent Raman Spectra of Tl[Ag(CN)2]: Evidence for Ligand-Unsupported Argentophilic Interactions

A. Omary, Mohammad; R. Webb, Thomas; Assefa, Zerihun; E. Shankle, G.; H. Patterson, Howard

doi:10.1021/ic970694l

Public

Crystal Structure, Electronic Structure, and Temperature-Dependent Raman Spectra of Tl[Ag(CN)2]: Evidence for Ligand-Unsupported Argentophilic Interactions

Published in Inorganic Chemistry • Mar 1, 1998

Authors:

Mohammad A. Omary

Thomas R. Webb

Zerihun Assefa

Abstract

The structure of thallium dicyanoargentate(I) has been determined crystallographically. The crystal structure shows an Ag-Ag distance of 3.11 Å. This is the shortest Ag-Ag distance reported for any silver dicyanide salt whose crystal structure has been determined. Raman spectra of the compound show ...

Subject

Chemistry

Monoclinic crystal system

Crystallography

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