Interplay between spin-crossover and luminescence in a multifunctional single crystal iron( <scp>ii</scp> ) complex: towards a new generation of molecular sensors

Benaicha, Bouabdellah; Do, Khanh; Yangui, Aymen; Pittala, Narsimhulu; Lusson, A.; Sy, Mouhamadou; Bouchez, Guillaume; Fourati, H.; J. Gómez‐García, Carlos; Triki, Smaı̈l; Boukheddaden, Kamel

doi:10.1039/c9sc02331c

Public

Interplay between spin-crossover and luminescence in a multifunctional single crystal iron( ii ) complex: towards a new generation of molecular sensors

Published in Chemical Science • Jan 1, 2019

Authors:

Bouabdellah Benaicha

Khanh Do

Aymen Yangui

Abstract

We present a new example of a mononuclear iron(ii) complex exhibiting a correlated spin-crossover (SCO) transition and strong fluorescence, whose coordination sphere is saturated, for the first time, by six phosphorescent ligands. The interplay between SCO and light emission properties in the therma...

Subject

Spin crossover

Phosphorescence

Luminescence

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