Synthesis of a two-dimensional organic-inorganic bismuth iodide metalate through in situ formation of iminium cations.

N, Dehnhardt; JN, Luy; M, Szabo; M, Wende; R, Tonner; J, Heine

doi:10.1039/c9cc06625j

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Synthesis of a two-dimensional organic-inorganic bismuth iodide metalate through in situ formation of iminium cations.

Shared by NobleBlocks on Dec 1, 2019 • 12:00 AM UTC

Authors:

Dehnhardt N

Luy JN

Szabo M

Abstract

(Me2C[double bond, length as m-dash]NMe2)Bi2I7 represents a new layered organic-inorganic iodido bismuthate. It displays an unprecedented anion topology, a low band gap and good stability. Advanced electronic structure analysis finds the II interactions to be decisive for the compound's structural a...

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