Valine derived poly (acetylenes) as versatile chiral lyotropic liquid crystalline alignment media for RDC-based structure elucidations.

A, Krupp; M, Noll; M, Reggelin

doi:10.1002/mrc.5003

Public

Valine derived poly (acetylenes) as versatile chiral lyotropic liquid crystalline alignment media for RDC-based structure elucidations.

Shared by NobleBlocks on Feb 11, 2020 • 12:00 AM UTC

Authors:

Krupp A

Noll M

Reggelin M

Abstract

Anisotropic samples of lyotropic liquid crystalline (LLC) phases of valine derived polyaryl acetylenes were employed as chiral alignment media for the measurement of residual dipolar couplings (RDCs) of 12 small, chiral, organic molecules. The quadrupolar splitting of the deuterium signal of CDCl3 c...

Subject

Polyacetylenes

Nmr Spectroscopy

Computational Chemistry

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