Lability of Ta–NHC adducts as a synthetic route towards heterobimetallic Ta/Rh complexes

Mohan Srivastava, Ravi; Alessandra Quadrelli, Elsje; Camp, Clément

doi:10.1039/d0dt00344a

Public

Lability of Ta–NHC adducts as a synthetic route towards heterobimetallic Ta/Rh complexes

Published in Dalton Transactions • Jan 1, 2020

Authors:

Ravi Mohan Srivastava

Elsje Alessandra Quadrelli

Clément Camp

Abstract

We report the synthesis and characterization of a series of original tantalum/rhodium heterobimetallic species assembled by a bifunctional alkoxy-N-heterocyclic carbene (NHC) ligand platform (noted L). The heterotrimetallic [Ta(CH2tBu)(CHtBu)(μ-L)Rh2(COD)2Cl2]n, 2, and heterobimetallic [Ta(μ-L)(CHtB...

Subject

Adduct

Chemistry

Reactivity (psychology)

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