Co-immobilization of a Rh Catalyst and a Keggin Polyoxometalate in the UiO-67 Zr-Based Metal–Organic Framework: In Depth Structural Characterization and Photocatalytic Properties for CO<sub>2</sub> Reduction

Benseghir, Youven; Lemarchand, Alex; Duguet, Mathis; Mialane, Pierre; Gómez-Mingot, María; Roch‐Marchal, Catherine; Pino, Thomas; Ha‐Thi, Minh‐Huong; Haouas, Mohamed; Fontecave, Marc; Dolbecq, Anne; Sassoye, Capucine; Mellot‐Draznieks, Caroline

doi:10.1021/jacs.0c02425

Public

Co-immobilization of a Rh Catalyst and a Keggin Polyoxometalate in the UiO-67 Zr-Based Metal–Organic Framework: In Depth Structural Characterization and Photocatalytic Properties for CO2 Reduction

Published in Journal of the American Chemical Society • May 7, 2020

Authors:

Youven Benseghir

Alex Lemarchand

Mathis Duguet

Abstract

The Keggin-type polyoxometalate (POM) PW12O403– and the catalytic complex Cp*Rh(bpydc)Cl2 (bpydc = 2,2′-bipyridine-5,5′-dicarboxylic acid) were coimmobilized in the Zr(IV) based metal organic framework UiO-67. The POM is encapsulated within the cavities of the MOF by in situ synthesis, and then, the...

Subject

Polyoxometalate

Chemistry

Catalysis

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