Potassium Poly(Heptazine Imide): Transition Metal‐Free Solid‐State Triplet Sensitizer in Cascade Energy Transfer and [3+2]‐cycloadditions

Savateev, Aleksandr; V. Tarakina, Nadezda; Strauß, Volker; Hussain, Tanveer; ten Brummelhuis, Katharina; Manuel Sánchez Vadillo, José; Markushyna, Yevheniia; Mazzanti, Stefano; P. Tyutyunnik, А.; Walczak, Ralf; Oschatz, Martin; M. Guldi, Dirk; Karton, Amir; Antonietti, Markus

doi:10.1002/anie.202004747

Public

Potassium Poly(Heptazine Imide): Transition Metal‐Free Solid‐State Triplet Sensitizer in Cascade Energy Transfer and [3+2]‐cycloadditions

Published in Angewandte Chemie International Edition • May 16, 2020

Authors:

Aleksandr Savateev

Nadezda V. Tarakina

Volker Strauß

Abstract

Abstract Polymeric carbon nitride materials have been used in numerous light‐to‐energy conversion applications ranging from photocatalysis to optoelectronics. For a new application and modelling, we first refined the crystal structure of potassium poly(heptazine imide) (K‐PHI)—a benchmark carbon nit...

Subject

Excited state

Photochemistry

Photocatalysis

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