<i>Operando</i> Investigation of Toluene Oxidation over 1D Pt@CeO<sub>2</sub> Derived from Pt Cluster-Containing MOF

Wang, Qingyue; Li, Yuxin; Serrano-Lotina, Ana; Han, Wei; Portela, Raquel; Wang, Ruixuan; Á. Bañares, Miguel; Lun Yeung, King

doi:10.1021/jacs.0c08640

Public

Operando Investigation of Toluene Oxidation over 1D Pt@CeO2 Derived from Pt Cluster-Containing MOF

Published in Journal of the American Chemical Society • Dec 15, 2020

Authors:

Qingyue Wang

Yuxin Li

Ana Serrano-Lotina

Abstract

A unique 1D nanostructure of Pt@CeO 2 –BDC was prepared from Pt@CeBDC MOF. The Pt@CeO 2 –BDC was rich in oxygen vacancies (i.e., XPS O β /(O α + O β ) = 39.4%), and on the catalyst, the 2 nm Pt clusters were uniformly deposited on the 1D mesoporous polycrystalline CeO 2 . Toluene oxidation was condu...

Subject

Chemistry

Catalysis

Adsorption

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