Gallium and indium complexes with new hexadentate bis(semicarbazone) and bis(thiosemicarbazone) chelators

Prado, V.S.; C.F. Leitao, Renan; Silva, Francisco; Gano, Lurdes; C. Santos, Isabel; Luiz Navarro Marques, Fábio; Paulo, António; M. Deflon, Victor

doi:10.1039/d0dt04028b

Public

Gallium and indium complexes with new hexadentate bis(semicarbazone) and bis(thiosemicarbazone) chelators

Published in Dalton Transactions • Jan 1, 2021

Authors:

V.S. Prado

Renan C.F. Leitao

Francisco Silva

Abstract

The synthesis of two new hexadentate potentially tetra-anionic acyclic chelators, an N2O4-donor bis(semicarbazone) (H4bsc) and an N2O2S2-donor bis(thiosemicarbazone) (H4btsc), is described. Coordination reactions of the ligands with gallium and indium precursors were investigated and yielded the com...

Subject

Semicarbazone

Chemistry

Indium

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