We report two new poly-small-molecule acceptors, PYN-BDT and PYN-BDTF, which serve, by virtue of their π-extended naphthalene rings, as broad optical cross-section macromolecular absorbers (extending to ∼900 nm; Δ E opticalgap = 1.38 eV) in all-polymer solar cells (APSCs). APSCs fabricated by blendi...
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