Unveiling the Electrooxidation of Urea: Intramolecular Coupling of the N−N Bond

Chen, Wei; Xu, Leitao; Zhu, Xiaorong; Huang, Yucheng; Wang, Zhou; Wang, Dongdong; Zhou, Yangyang; Du, Shiqian; Li, Qiling; Xie, Chao; Li, Tao; Dong, Chung‐Li; Liu, Jilei; Wang, Yanyong; Chen, Ru; Su, Hui; Chen, Chen; Zou, Yuqin; Li, Yafei; Liu, Qinghua; Wang, Shuangyin

doi:10.1002/anie.202015773

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Unveiling the Electrooxidation of Urea: Intramolecular Coupling of the N−N Bond

Published in Angewandte Chemie International Edition • Dec 25, 2020

Authors:

Wei Chen

Leitao Xu

Xiaorong Zhu

Abstract

Abstract The nitrogenous nucleophile electrooxidation reaction (NOR) plays a vital role in the degradation and transformation of available nitrogen. Focusing on the NOR mediated by the β‐Ni(OH)2 electrode, we decipher the transformation mechanism of the nitrogenous nucleophile. For the two‐step NOR,...

Subject

Chemistry

Nucleophile

Intramolecular force

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