Characterization and Luminescence Properties of Lanthanide-Based Polynuclear Complexes Nanoaggregates.

Natur F, Le; G, Calvez; JP, Guégan; Pollès L, Le; X, Trivelli; K, Bernot; C, Daiguebonne; C, Neaime; K, Costuas; F, Grasset; O, Guillou

doi:10.1021/acs.inorgchem.5b00947

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Characterization and Luminescence Properties of Lanthanide-Based Polynuclear Complexes Nanoaggregates.

Shared by NobleBlocks on May 29, 2015 • 12:00 AM UTC

Authors:

Le Natur F

Calvez G

Guégan JP

Abstract

For the first time, hexanuclear complexes with general chemical formula [Ln6O(OH)8(NO3)6(H2O)n](2+) with n = 12 for Ln = Sm-Lu and Y and n = 14 for Ln = Pr and Nd were stabilized as nanoaggregates in ethylene glycol (EG). These unprecedented nanoaggregates were structurally characterized by (89)Y an...

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