Rational Preparation of Well-Defined Multinuclear Iridium–Aluminum Polyhydride Clusters and Comparative Reactivity

Escomel, Léon; Soulé, Naïme; Robin, Emmanuel; Del Rosal, Iker; Maron, Laurent; Jeanneau, Erwann; Thieuleux, Chloé; Camp, Clément

doi:10.1021/acs.inorgchem.1c03120

Public

Rational Preparation of Well-Defined Multinuclear Iridium–Aluminum Polyhydride Clusters and Comparative Reactivity

Published in Inorganic Chemistry • Jan 24, 2022

Authors:

Léon Escomel

Naïme Soulé

Emmanuel Robin

Abstract

We report an original alkane elimination approach, entailing the protonolysis of triisobutylaluminum by the acidic hydrides from Cp*IrH4. This strategy allows access to a series of well-defined tri- and tetranuclear iridium aluminum polyhydride clusters, depending on the stoichiometry: [Cp*IrH3Al(iB...

Subject

Iridium

Chemistry

Protonolysis

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