Degradable vinyl polymer particles by radical aqueous emulsion copolymerization of methyl methacrylate and 5,6-benzo-2-methylene-1,3-dioxepane

Galanopoulo, Paul; Sinniger, L.; Gil, Noémie; Gigmès, Didier; Lefay, Catherine; Guillaneuf, Yohann; Lages, Maëlle; Nicolas, Julien; D’Agosto, Franck; Lansalot, Muriel

doi:10.1039/d3py00040k

Public

Degradable vinyl polymer particles by radical aqueous emulsion copolymerization of methyl methacrylate and 5,6-benzo-2-methylene-1,3-dioxepane

Published in Polymer Chemistry • Jan 1, 2023

Authors:

Paul Galanopoulo

L. Sinniger

Noémie Gil

Abstract

Aqueous emulsion copolymerization of methyl methacrylate (MMA) and 5,6-benzo-2-methylene-1,3-dioxepane (BMDO) leads to stable particles of PMMA bearing in-chain ester units that can be cleaved under basic conditions.

Subject

Copolymer

Methyl methacrylate

Emulsion

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