Vanadium Alumanyl Complex: Synthesis, Characterization, Reactivity, and Application as a Catalyst for C–H Alumanylation of Alkenes

Zatsepin, Pavel; Moriyama, Takumi; Chen, Chaoqi; Muratsugu, Satoshi; Tada, Mizuki; Yamashita, Makoto

doi:10.1021/jacs.3c13418

Public

Vanadium Alumanyl Complex: Synthesis, Characterization, Reactivity, and Application as a Catalyst for C–H Alumanylation of Alkenes

Published in Journal of the American Chemical Society • Jan 27, 2024

Authors:

Pavel Zatsepin

Takumi Moriyama

Chaoqi Chen

Abstract

A complex containing a V–Al bond is described. This species can be prepared by either transmetalation of a previously disclosed alumanylpotassium with Cp 2 VCl or photolytic oxidative alumination of Cp 2 V using the corresponding dialumane. Reaction of the resulting V–Al complex with H 2 gave a Cp 2...

Subject

Chemistry

Reactivity (psychology)

Transmetalation

Finding related papers...

Discussions

(0)

No comments yet

Be the first to share your thoughts!