Merging gold plasmonic nanoparticles and
                    <scp>l</scp>
                    -proline inside a MOF for plasmon-induced visible light chiral organocatalysis at low temperature

Kushnarenko, A.; Zabelina, A.; Guselnikova, O.; Miliutina, E.; Vokatá, B.; Zabelin, D.; Burtsev, V.; Valiev, R.; Kolska, Z.; Paidar, M.; Sykora, V.; Postnikov, P.; Svorcik, V.; Lyutakov, O.

doi:10.1039/d3nr04707e

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Merging gold plasmonic nanoparticles and l -proline inside a MOF for plasmon-induced visible light chiral organocatalysis at low temperature

Shared by NobleBlocks on Jan 1, 2024 • 12:00 AM UTC

Authors:

A. Kushnarenko

A. Zabelina

O. Guselnikova

Abstract

Plasmon-active centers (AuNPs) and chiral catalyst (proline) were immobilized in close vicinity using UiO-66–NH 2 for aldol reaction. The reaction was performed under illumination and plasmon triggering allows achieving a high value of enantioselectivity and reaction yield at −20°.

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