A microporous three-dimensional hydrogen-bonded organic framework (HOF-5) has been constructed from a new organic linker 4,4',4″,4‴-tetra(2,4-diamino-1,3,5-triazin-6-yl)tetraphenylethene. Activated HOF-5a exhibits a stepwise N2 adsorption isotherm at 77 K, suggesting framework flexibility. The struc...
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